When advertisements talk about percentage off, they're providing two prices. The higher price is meant to anchor your judgment of the item's value and your estimates of what other stores will charge, while the lower price is meant to seem cheap by comparison. However, the higher price is not required to be reasonable, and in fact, it usually isn't; stores often mark items up to ridiculous prices just so they can bring them back down again with sales.
From Tversky and Khaneman's "The Framing of Decisions and the Psychology of Choice" (Science, Vol. 211, No. 4481, 1981):
This one's a killer. Money is supposed to be fungible, but these observations really highlight how difficult it is to really behave as if you believed that. So, aspiring rationalists, how might we combat this in ourselves? Maybe it would help to consciously convert between money and time: if you value your time at 25 $/hr, then the cost of a twenty-minute drive is 25 $/hr * (1/3) hr = $8.33 > $5, so you buy the calculator in front of you in either case. So this heuristic at least takes care of the calculator problem, although I would guess it fails miserably in other contexts, I currently know not which.
Another takeaway lesson is to ignore advertisements boasting that a product is currently such-and-such percent off. We don't care about the percentage! How many minutes are you saving?