These supplements are unlikely to help a balanced diet, there is little evidence they do, and there are studies which have indicated actual harm from the consumption of multivitamins
What I'd really like to see is a study comparing unhealthy diets plus multivitamins to just the unhealthy diet.
Without having looked at the actual studies in detail, it seems that even several of the "no benefit" studies report multivitamins to be beneficial when one does have an otherwise unhealthy diet.
...Similarly, a 2006 report for the United States Department of Health and Human Services concluded that "regular supplementation with a single nutrient or a mixture of nutrients for years has no significant benefits in the primary prevention of cancer, cardiovascular disease, cataract, age-related macular degeneration or cognitive decline.&
Full essay: http://www.gwern.net/Melatonin