gwern comments on Case study: Melatonin - Less Wrong
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Don't teenagers have brain-chemistry that makes them have trouble getting to sleep at a reasonable hour? I'm not finding a good reference, but I remember reading that, and that the effect doesn't apply to children.
The circadian link is to a gatewayed article; you can find a public copy at http://www.thefreelibrary.com/Sleepy+teens+haven%27t+got+circadian+rhythm.-a0134623686