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Yvain comments on Antagonizing Opioid Receptors for (Prevention of) Fun and Profit - Less Wrong
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I've heard good things about baclofen too, but I haven't looked at in in depth. If you've read that book, I'd be really interested in seeing a post about the science behind it.
I didn't remember enough to answer your question, but I found a summary, with self-experimentation anecdotes in the comments.