Chronos comments on Procedural Knowledge Gaps - Less Wrong
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To my knowledge, this is how it works, but I might be missing a detail or two (never had to do it completely on my own).
1) Start with the car with the dead battery first. Expose the terminals of the battery - usually there are plastic covers to prevent anything from touching the metal terminals. Connect the jumper cables to both of these terminals. Jumper cables have a red side and a black side. You don't have to match red with the positive or negative terminal, but you will have to remember how you matched them. I.e., remember whether red is positive or negative.
2) Now go to the car with the good battery and make sure it's started and running. Connect the jumper cables to the terminals of the battery of that car in the same way that you connected them to the first car. I.e., if the red side was connected to the positive terminal on the first car, do the same on the second car.
3) Wait. It takes a few minutes to recharge a dead battery.
4) Try to start the car with the dead battery. You can do this with the jumper cables still connected. If it doesn't work, return to 3)
5) If it starts, disconnect the jumper cables.
A couple of things: don't touch the metal ends of the cables or the battery terminals. You could be in for a shock.
If the battery of a car dies, it's likely because the alternator, which recharges the battery, went out. Because of this, it's a good idea to give the dead battery a decent charge before disconnecting so that the car you're giving a jump can make it to wherever it's going (hopefully a mechanic!).
edit: and it's not my fault if you use these instructions and get caught in an infinite loop :)
I was taught a slightly different procedure, which is the same as the one listed as the first result on Google for "jumper cables":
The site I linked to makes the point that steps 6-7-8 in my procedure can damage the acceptor's alternator. It recommends letting the donor run for a bit longer than my step 6 requires, then (8a) shutting off the donor, (8b) disconnecting the cables entirely, and only then (7) starting the acceptor. Whether or not this method works would depend on the state of the battery (it may fail for a poor but working battery) and the weather (it may fail below, say, 10°F / -12°C).
(Note: lead-acid batteries are damaged by letting them discharge fully, because the cathodes and anodes are both transformed into the same material, lead sulfate. Once that happens, it becomes far more difficult to recharge the battery and you're better off just buying a new one. Even if your battery won't take a charge, a jump start can get you to a store that sells new automotive batteries -- the battery is only needed to turn the engine through the first few cycles, and the alternator will provide all needed electricity once the engine is turning fast enough.)