Peterdjones comments on Seeing Red: Dissolving Mary's Room and Qualia - Less Wrong
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Not really; it just means that our ability to imagine sensory experiences is underpowered. There are limits to what you can imagine and call up in conscious experience, even of things you have experienced. A person could imagine what it would be like to be betrayed by a friend, and yet still not be able to experience the same "qualia" as they would in the actual situation.
So, you can know precisely which neurons should fire to create a sensation of red (or anything else), and yet not be able to make them fire as a result.
Mere knowledge isn't sufficient to recreate any experience, but that's just a fact about the structure and limitations of human brains, not evidence of some special status for qualia. (It's certainly not an argument for non-materialism.)
Why does Mary need to imagine red in order to know what it looks like? If the physical understanding she already has accounts for it, then she should be able to figure it out from that, as per the Dennett response. Like several people in this thread, you are tacitly assuming that there is something special about qualia, such that they need to be imagined or instantiated in order to be known -- something that is unique about them, even though they are ultimately physical like everything else.