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gwern comments on Fix My Head - Less Wrong
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I believe anhydrous caffeine powder, as the name indicates, dissolves nicely into water. (I seem to recall this being the case for me, although I cannot test it now since I long ago turned all the caffeine powder into pills.)
It does dissolve reasonably into water, but tastes pretty terrible. Can dilute it with fruit juice if that's a problem, or just ignore it.