James_Miller comments on How would you take over Rome? - Less Wrong
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Augustus would quickly capture you if you produced black powder. Tiberius would torture you for the formula and then kill you and nearly everyone who he suspected you might have given the formula to.
See:
Yes, that's a cool story, but it's not like innovation stopped in the Roman empire.
Is this story considered likely true? Did he invent plastic?
Apparently, Pliny himself was skeptical.
I'm not sure.