I'm not sure I understand what you mean. If I already had strong reason to think that the whole of Catholicism was true, then I couldn't just say "well, but I don't want same-sex romance prohibited, so I'll decide not to believe in Catholicism." That would be fallacious reasoning. But if I start off fairly certain that there's nothing wrong with same-sex romance but am also looking for some sort of theistic tradition that makes sense given what I already know, then Catholicism's views on sexuality would seem to count against it.
Perhaps you could compare this issue to the "it all adds up to normality" sentiment. Even if I decide I have to abandon my old theory of gravity, my new theory better be one that has pencils falling down and not up when I drop them. Likewise, even if I have to abandon my general thoughts on theism, I had better not pick a religious tradition that conflicts with strongly held moral sentiments of which I am still reasonably confident. What's the fallacy there?
But if I start off fairly certain that there's nothing wrong with same-sex romance but am also looking for some sort of theistic tradition that makes sense given what I already know, then Catholicism's views on sexuality would seem to count against it.
Depends on how strong my evidence is for this position. If it's nothing stronger than "I can't think of any reason why same-sex romance is bad", then it doesn't take much evidence for Catholicism to overcome it.
I recently learned that a friend of mine, and a long-time atheist (and atheist blogger), is planning to convert to Catholicism. It seems the impetus for her conversion was increasing frustration that she had no good naturalistic account for objective morality in the form of virtue ethics; that upon reflection, she decided she felt like morality "loved" her; that this feeling implied God; and that she had sufficient "if God, then Catholicism" priors to point toward Catholicism, even though she's bisexual (!) and purports to still feel uncertain about the Church's views on sexuality. (Side note: all of this information is material she's blogged about herself, so it's not as if I'm sharing personal details she would prefer to be kept private.)
First, I want to state the rationality lesson I learned from this episode: atheists who spend a great deal of their time analyzing and even critiquing the views of a particular religion are at-risk atheists. Eliezer's spoken about this sort of issue before ("Someone who spends all day thinking about whether the Trinity does or does not exist, rather than Allah or Thor or the Flying Spaghetti Monster, is more than halfway to Christianity."), but I guess it took a personal experience to really drive the point home. When I first read my friend's post, I had a major "I notice that I am confused" moment, because it just seemed so implausible that someone who understood actual atheist arguments (as opposed to dead little sister Hollywood Atheism) could convert to religion, and Catholicism of all things. I seriously considered (and investigated) the possibility that her post was some kind of prank or experiment or otherwise not sincere, or that her account had been hijacked by a very good impersonator (both of these seem quite unlikely at this point).
But then I remembered how I had been frustrated in the past by her tolerance for what seemed like rank religious bigotry and how often I thought she was taking seriously theological positions that seemed about as likely as the 9/11 attacks being genuinely inspired and ordained by Allah. I remembered how I thought she had a confused conception of meta-ethics and that she often seemed skeptical of reductionism, which in retrospect should have been a major red flag for purported atheists. So yeah, spending all your time arguing about Catholic doctrine really is a warning sign, no matter how strongly you seem to champion the "atheist" side of the debate. Seriously.
But second, and more immediately, I wonder if anybody has advice on how to handle this, or if they've had similar experiences with their friends. I do care about this person, and I was devastated to hear this news, so if there's something I can do to help her, I want to. Of course, I would prefer most that she stop worrying about religion entirely and just grok the math that makes religious hypotheses so unlikely as to not be worth your time. But in the short term I'd settle for her not becoming a Catholic, and not immersing herself further in Dark Side Epistemology or surrounding herself with people trying to convince her that she needs to "repent" of her sexuality.
I think I have a pretty good understanding of the theoretical concepts at stake here, but I'm not sure where to start or what style of argument is likely to have the best effect at this point. My tentative plan is to express my concern, try to get more information about what she's thinking, and get a dialogue going (I expect she'll be open to this), but I wanted to see if you all had more specific suggestions, especially if you've been through similar experiences yourself. Thanks!