Why is it illegal to buy or administer anesthetics without a medical license? Just defending the monopoly or is there some legitimate reason?
It's not, strictly speaking. I can buy OTC anesthetics myself; lidocaine is in many sunburn creams, for example, and I can apply them to somebody without a medical license.
However, the anesthetics which are used during major surgery are (as far as I know, all) controlled substances, on account of their narcotic properties.
http://www.theverge.com/2012/8/8/3177438/cyborg-america-biohackers-grinders-body-hackers