That's asking a fair amount from people I only know over the Internet. I could count on one hand the number of people that I expect a >50% chance of response (even refusal) if I asked them for this kind of help on this site.

I, or another person, would appear to be volunteering reading and offering relatively unskilled commentary on short blurbs of rationality related text. I know I personally already do that for fun when I post here, I just somewhat randomly select which items to reply to. This would essentially be what I would already be doing except people would be sending me what to read, so it doesn't seem to be a lot of work for me at all, unless the response was unexpectedly massive.

I guess what I am considering is like Jsalvatier's help desk at http://lesswrong.com/lw/eto/lesswrong_help_desk_free_paper_downloads_and_more/ but at a lower level for people who have simple questions like "Why was this downvoted?"

And I'm not sure anything is wrong with that.

Can you go into more detail?