There's one expression of this idea I like because it uses the partial equilibrium supply & demand model that introductory microeconomics classes always use, and it's a reasonably easy formulation to follow if one knows that model. (It also illustrates a danger of doing back-of-a-napkin partial equilibrium analysis for a single market when that market's big enough to have a big knock-on effect on another market.)
I'm lifting this from Robin Hahnel (Journal of Economic Issues, 41(4), pp. 1139-1159), although he says he got it from Axel Leijonhufvud:
Consider a labor market and a goods market. Assume that if either market is out of equilibrium the excess supply or excess demand in that market will eventually lead to wage or price adjustments leading that market to its equilibrium. Now assume that while the goods market is initially in equilibrium, the labor market is not because the wage rate is temporarily higher than the equilibrium wage. While the excess supply in the labor market will generate equilibrating forces pushing the wage rate down toward its equilibrium, suppose it does not reach its equilibrium immediately, and in the meantime labor contracts are struck at a wage rate that is still higher than the equilibrium wage. If the labor demand curve is elastic this will result in lower labor income than would have been the case if the wage rate had reached its equilibrium. But the demand curve in the goods market was premised on the (implicit) assumption that the labor market was in equilibrium, and therefore that labor income was higher than it actually will be. When we reconstruct the demand curve in the goods market based on the actual outcome in the labor market, where labor income is lower than it would have been had the labor market been in equilibrium, we get an actual goods demand curve to the left of the one anticipated. No matter how quickly or slowly the price in the goods market adjusts to the resulting excess supply, we will get a drop in sales and revenues in the goods market.
But lower sales and revenues in the goods market will decrease the demand for labor in the labor market. The demand curve we originally drew in the labor market was premised on the (implicit) assumption that we had reached the equilibrium outcome in the goods market. Now that sales and revenues are lower in the goods market, when we reconstruct the demand for labor curve based on the new, actual outcome in the goods market, we get a new demand for labor curve to the left of the initial one. No matter how quickly or slowly the wage rate adjusts to the new excess supply, employment and labor income will drop, further depressing the actual demand for goods in the goods market. Instead of remaining in equilibrium in the goods market and moving toward the higher, equilibrium level of employment in the labor market, we move out of equilibrium in the goods market and even farther away from equilibrium levels of employment in the labor market.
I've always found that learning new areas always goes a lot better if you start with a key insight of what the field is about. Often this is not presented or explained at the beginning of the course, and you have to deduce it later on.
For instance, I would have better grasped the epsilon-delta definition of a limit if the instructor had started with something like:
Similarly, I would have made more rapid progress with Gödel's theorems if, before giving the formal definition of Gödel numbering and of the provability symbol □, someone had clarified that direct and indirect self-reference was a problem. If a formal system of a certain complexity can talk about its own structure, even without "realising" that it's doing so, problems will arise. Some of my other key insights in the field can be found in my post here.
So when I do stumble upon a key insight, I want to share it. I've found some recently in Keynesian economics, giving me a much better grasp of what makes that economic theory tick, and which would be my point of entry should I ever study the subject in detail. The two key insights are:
Of course, Keynesianism makes great use of irrationality or partial rationality of the agents (such as the stickiness of wages or the irrationality of bubbles), but it was a revelation that rational models, full of Homo Economicus, could still produce excess unemployment.
This seemed intuitively very odd. After all, if there is unemployment, wages should fall, making it more attractive to hire workers. Therefore the equilibrium should be that everyone who wanted to work at the wages available should work. And this is not only an equilibrium, but an attractor: free-floating wages should move the economy towards the equilibrium.
But this lecture presented the rest of the argument. In a closed economy, investment (by firms) plus consumption (by individuals) must be equal to the total production of the economy - you can't sell stuff to thin air. Similarly, the amounts sold by firms translate into income for firms, shareholders and workers - you can't generate income without selling to someone. Over the short term, things can move out of equilibrium (people can increase or cash in their savings), but over the long term it has to balance.
That equilibrium is also an attractor. So we have two equilibrium processes - the wage changes, and the consumptions plus investment equality. Notice, though, that they interact! As wages rise and fall, people's incomes rise and fall, and hence their consumption, which feeds through to the incomes of firms and hence to their own levels of investment and salaries...
The question then, is whether there exists a joint equilibrium for both processes at once (more properly, since consumption consists of many markets, a general equilibrium for the whole economy). We'd want an equilibrium that was also an attractor, since we'd want to move to that state. In some circumstances, such attracting joint equilibriums exist - but in others, they don't.
So, at least in the model, excess unemployment can persist in the presence of fully rational agents.