Decius comments on To what degree do you model people as agents? - Less Wrong
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I haven't codified the exact distinction that I make between those two concepts; in the case of material science, a 'problem' would be a pressure vessel at a low temperature containing high pressure; the failure mode of such a problem would be brittle fracture.
In this case it might also have made sense to call it a class of problems; each instance is different enough that a general solution would be different in nature from a series of specific solutions which combined covered every individual exemplified case.