nshepperd comments on Entropy and Temperature - Less Wrong

26 Post author: spxtr 17 December 2014 08:04AM

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Comment author: DanielLC 18 December 2014 04:18:47AM 2 points [-]

Average kinetic energy always corresponds to average kinetic energy, and the amount of energy it takes to create a marginal amount of entropy always corresponds to the amount of energy it takes to create a marginal amount of entropy. Each definition corresponds perfectly to itself all of the time, and applies to the other in the case of idealized objects. How is one more general?

Comment author: nshepperd 18 December 2014 06:15:54AM *  1 point [-]

Two systems with the same "average kinetic energy" are not necessarily in equilibrium. Sometimes energy flows from a system with lower average kinetic energy to a system with higher average kinetic energy (eg. real gases with different degrees of freedom). Additionally "average kinetic energy" is not applicable at all to some systems, eg. ising magnet.