Gondolinian comments on Harry Potter and the Methods of Rationality discussion thread, February 2015, chapter 113 - Less Wrong
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It has been established that air can't be Transfigured due to the constant motion of its particles; they don't hold still long enough for you to Transfigure them.
Is there an easy-to-link-to source for this? Not that I don't believe you, I just want to make sure there aren't any non-obvious or obvious-in-hindsight alternative interpretations.
Ch. 28:
This isn't conclusive, though. That failed attempt is before he sorts out partial transfiguration. However:
It would need to be fairly clear, I think, that Harry was re-purposing an old technique and not doing something new.
The first rule of Transfiguration: you do not guess.
Harry proposed a hypothesis, but no further testing was committed. Without knowledge of PT, I'd rate the inability to transfigure all air (as a conceptually-singular entity) as an equally (or more) probable explanation.