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Lumifer comments on How to grow faster - Less Wrong
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That combination usually goes by the name of "tea".
That suggests you never tried it. Seriously do - a cup of tea or three does about nothing (for me) a 150mg l-t pill and an average coffeine pill does.
Theanine is about 1% of the dry weight of tea leaves, so your 150mg pill corresponds to about 15g of tea (7-8 teabags, more or less) which is a lot for most people.
It's just a dosage difference.