I think that's basically the point - the argument is technically valid, but it is wrong, and you got there by using "human" wrong in the first place.
Socrates is clearly human, and the definition on hand is "bipedal, featherless, and mortal". If Socrates is mortal, then he is susceptible to hemlock. When Socrates takes hemlock and survives, you can't change the definition of "human" to "bipedal, featherless, not mortal". You're still using the word "human" wrong.
What's telling here is that you don't say "Socrates is not human" because you already know he is. If you do go down that route, even though your arguments are correct the conclusion will be intuitively wrong - just another valid but incorrect argument. There are undefined characteristics regarding what it is to be human which carry significantly more weight than the definition itself, and instead of encapsulating them in the definition you've tried to ignore them - tried to make reality fit your definition rather than the other way around.
I think that's basically the point - the argument is technically valid, but it is wrong, and you got there by using "human" wrong in the first place.
Well, the problem with the argument 'Socrates is human, humans are immortal, therefore Socrates is immortal' is that the second premise is false. Is it because the word 'human' is used wrongly in the argument? I don't see how. If the problem is that my definition of 'human' is wrong, this still seems to be just a problem of having false beliefs about the world, not an incorrect use of language.
Some reader is bound to declare that a better title for this post would be "37 Ways That You Can Use Words Unwisely", or "37 Ways That Suboptimal Use Of Categories Can Have Negative Side Effects On Your Cognition".
But one of the primary lessons of this gigantic list is that saying "There's no way my choice of X can be 'wrong'" is nearly always an error in practice, whatever the theory. You can always be wrong. Even when it's theoretically impossible to be wrong, you can still be wrong. There is never a Get-Out-Of-Jail-Free card for anything you do. That's life.
Besides, I can define the word "wrong" to mean anything I like - it's not like a word can be wrong.
Personally, I think it quite justified to use the word "wrong" when:
Everything you do in the mind has an effect, and your brain races ahead unconsciously without your supervision.
Saying "Words are arbitrary; I can define a word any way I like" makes around as much sense as driving a car over thin ice with the accelerator floored and saying, "Looking at this steering wheel, I can't see why one radial angle is special - so I can turn the steering wheel any way I like."
If you're trying to go anywhere, or even just trying to survive, you had better start paying attention to the three or six dozen optimality criteria that control how you use words, definitions, categories, classes, boundaries, labels, and concepts.