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The problem with many of the government labs is that they want post docs and not employees, and I'd rather just skip that and start as an actual employee somewhere.
In addition many of the places I've applied (many of which you listed) have very long application processes (months) which means I'm in the dark as to whether I'll get zero offers or an offer from every place which I applied. Therefore I'd like to be cautious and cultivate as many options as possible.
Lastly, I tend to get into situations like these (ones with big decisions and many unclear options) and end up realizing in retrospect that there were more interesting opportunities available than the one I took, but that I panicked and didn't properly explore the options. So I'm trying to make a serious effort of looking for and apply to 'out of the box' employment options.
Have you thought about big bucks in Si-valley or finance? I kind of envy physicists because I feel like they have the kind of math skills that lets them figure out anything from first principles.