The term "dark art" is usually used in these parts to mean something very different from this...
[EDITED some time after posting, to fix a typo.]
[EDITED again to add: when I wrote the above, the title was something about "the dark art of estimation"; it's been changed now. This also explains Dr_Manhattan's otherwise confusing question.]
Fermi problem
Link: en.wikipedia.org/wiki/Fermi_problem
Fermi Problem: Power developed at the eruption of the Puyehue-Cordón Caulle volcanic system in June 2011
Link: technologyreview.com/blog/arxiv/27140/
If you want to get better at doing rough mental calulcations, the following books might provide some valuable heuristics:
Street-Fighting Mathematics: The Art of Educated Guessing and Opportunistic Problem Solving
Link: web.mit.edu/newsoffice/2010/street-fight-0329.html
Secrets of Mental Math: The Mathemagician's Guide to Lightning Calculation and Amazing Math Tricks