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RichardKennaway comments on Entropy and Temperature - Less Wrong Discussion

26 Post author: spxtr 17 December 2014 08:04AM

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Comment author: RichardKennaway 21 January 2015 04:09:13PM 1 point [-]

If I know everything about that cup of water, but Alice doesn't, is the water at zero Kelvin for me but still hot for Alice?

And will we both predict the same result when someone puts their hand in it?

Comment author: Lumifer 21 January 2015 04:37:59PM 0 points [-]

Probably yes, but then I will have to say things like "Be careful about dipping your finger into that zero-Kelvin block of ice, it will scald you" X-)

Comment author: spxtr 22 January 2015 04:07:26AM 0 points [-]

It won't be ice. Ice has a regular crystal structure, and if you know the microstate you know that the water molecules aren't in that structure.

Comment author: Lumifer 22 January 2015 04:03:39PM 1 point [-]

So then temperature has nothing to do with phase changes?

Comment author: gjm 22 January 2015 04:43:37PM 1 point [-]

Temperature in the thermodynamic sense (which is the same as the information-theoretic sense if you have only ordinary macroscopic information) is the same as average energy per molecule, which has a lot to do with phase changes for the obvious reason.

In exotic cases where the information-theoretic and thermodynamic temperatures diverge, thermodynamic temperature still tells you about phase changes but information-theoretic temperature doesn't. (The thermodynamic temperature is still useful in these cases; I hope no one is claiming otherwise.)

Comment author: spxtr 22 January 2015 08:00:24PM 2 points [-]

You probably know this, but average energy per molecule is not temperature at low temperatures. Quantum kicks in and that definition fails. dS/dE never lets you down.

Comment author: gjm 22 January 2015 10:05:33PM 0 points [-]

Whoops! Thanks for the correction.

Comment author: Lumifer 22 January 2015 05:05:03PM 0 points [-]

Aha, thanks. Is information-theoretic temperature observer-specific?

Comment author: gjm 22 January 2015 05:18:38PM 0 points [-]
Comment author: dxu 22 January 2015 08:26:00PM 0 points [-]

I am somewhat amused that you linked to the same post on which we are currently commenting. Was that intentional?

Comment author: gjm 22 January 2015 10:02:00PM 0 points [-]

Actually, no! There have been kinda-parallel discussions of entropy, information, probability, etc., here and in the Open Thread, and I hadn't been paying much attention to which one this was.

Anyway, same post or no, it's as good a place as any to point someone to for a clarification of what notion of temperature I had in mind.