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DanArmak comments on [Link] Death with Dignity by Scott Adams - Less Wrong Discussion
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Which is one reason most opiates, and most other drugs you can easily overdose on and die (as opposed to water), are not legal to buy without prescription.
Actually, no, the reason why you can't buy opiates without a prescription is because they are addictive psychoactives.
You can very easily overdose on Tylenol (acetaminophen, paracetamol), but it will take you a while to die from liver failure. You can buy unlimited amount of Tylenol in every pharmacy.
Like I said, dangerous overdoses and side effects are one reason, not the only reason.
Which drugs are legal, and which don't require prescriptions, is in large part a matter of historical contingency, lobbying and politics. But there are other reasons too, and dangerous side effects or overdose effects are among the more important ones.