Yeah, car batteries can do about a kiloamp into a dead short so we can treat them as ideal voltage sources for this 'application'. However, even with wet hands and solid contact, 12 volts is too low to get much current flowing.
Soaking my hands in saturated salt water got my hand to hand resistance down to 10-20kohm (0.5-1ma), which is still at least a factor of 250 above the 40 ohm resistance you'd need to draw 300ma, which is the lower figure wiki gives for DC caused fibrillation. Putting one hand on either terminal didn't get me so much as a tingle.
I know tingle levels are possible when soaking for longer (hours) and 9v will tingle your tongue (2-4milliamps), but it seems exceedingly hard to get to a dangerous level, considering that most models I've seen had the internal resistance of people at hundreds of ohms (350 is the number that sticks in mind). Also nerves are somewhat AC coupled, which brings the fibrillation limit up and makes people push away from the source instead of clinging on.
I guess it might be possible for someone with thin skinned thoroughly soaked hands making good contact and having a poorly shielded sensitive heart, but I'd call it a 'freak accident'.
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The internal resistance of the body (and wet skin) is sufficient that it and the voltage are the relevant factors. Jimmy even went so far assume an ideal power source - as much current as 12v can get you. The resistance even without the benefit of dry skin is sufficient to keep the current that passes near the heart below the level that will result in fibrillation in healthy humans.
I would have to concur with Jimmy that death by car battery electrocution would qualify as 'freak accident'. If you want to kill yourself with a battery you could perhaps try balancing it on top of a door and closing it while your head is
According to Wikipedia, the threshold for fibrillation is 60 mA for AC, 300-500 mA for DC. On reflection, it seems I'd previously cached the AC value as the value for all currents, so that was skewing my argument.
Given these figures, a 1k Ohm total resistance (internal plus skin plus body) would lead to a 12 mA current (painful but not fibrillation-inducing), whereas 200 Ohms / 40 Ohms total resistance would be required for 12 VAC / VDC to be potentially lethal. So, yeah, now that I think about it, a car battery probably couldn't be lethal unless conductors were actually puncturing the skin and touching the bloodstream directly (or covering a HUGE amount of surface area). I retract my claim.
Edit: OH! Except that Wikipedia says the threshold for fibrillation is a mere 10 µA if the current is from electrodes that establish a circuit through the heart. THAT's the figure I'd seen before and cached in my head. Still, that's not a likely situation to arise when using jumper cables, so my claim remains retracted.