Are there actually any materials on Earth that are so rare and precious (and perhaps in danger of running out in the foreseeable future) that it would make sense to mine them from space?
By the way, the claim about aluminum sounds highly implausible to me. Aluminum accounts for about 8% of the Earth's crust by weight, and even if most of it is difficult to access, I would expect that more than the amount present on Eros would be extractable with methods much easier than any conceivable sort of asteroid mining.
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Now that's interesting! I didn't know that the prospects for helium-3 fusion are allegedly that good. Still, given the previous history of controlled fusion research, I'm inclined to be skeptical. Do you know of any critical references about the present 3He fusion research? All the references I've seen from a casual googling appear to be pretty optmistic about it.
I have no reference, but as far as I understand, deuterium-tritium fusion is easier to achieve than deuterium-helium-3. But deuterium-helium-3 seems cleaner and the energy produced is easier to harvest.
So I think that the first energy producing fusion reactor would be a deuterium-tritium one, and deuterium-helium-3 would come later.