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i77 comments on Open Thread: February 2010, part 2 - Less Wrong
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Fullmetal Alchemist Brotherhood has (SPOILER):
an almost literally unboxed unfriendly "AI" as main bad guy. Made by pseudomagical ("alchemy") means, but still.
It bugs me that people don't think of this one more often. It's basically an anime about how science affects the world and its practitioners.
(Disclaimer: Far too many convenient coincidences/idiot balls IIRC. It's a prime target for a rationalist rewrite.)