Entropy is in the mind in exactly the same sense that probability is in the mind. See the relevant Sequence post if you don't know what that means.
The usual ideal gas model is that collisions are perfectly elastic, so even if you do factor in collisions they don't actually change anything. Interactions such as van der Waals have been factored in. The ideal gas approximation should be quite close to the actual value for gases like Helium.
The usual ideal gas model is that collisions are perfectly elastic, so even if you do factor in collisions they don't actually change anything.
They don't change ANYTHING? Suppose I start with a gas of molecules all moving at the same speed but in different directions, and they have elastic collisions off the walls of the volume. If they do not collide with each other, they never "thermalize," their speeds stay the same forever as they bounce off the walls but not off each other. But if they do bounce off each other, the velocity distributi...
If it's worth saying, but not worth its own post (even in Discussion), then it goes here.
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