NancyLebovitz comments on Open Thread: May 2010 - Less Wrong
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Coffee and concentration experiment
Article about self-measurement
This doesn't mean you don't get a boost, but it might be worth checking.
My experience is quite similar to what is described in the first article -- no coffee leads to better concentration for me. The caffeine 'boost' I was talking about reduces my concentration but makes me more inclined to action -- I found it useful for breaking through procrastination periods. The effect of Red Bull on me is similar but more pronounced.
The effect seems to be physical, but I don't rule out placebo (and frankly, it's fine with me either way.)