There are lots of total orderings on the complex numbers. For example:
a + bi [>] c + di iff a >= c or (a = c and b >= d).
In fact, if you believe the axiom of choice there are "nice total orders" for any set at all.
Importantly, however, the complex numbers have no total ordering that respects addition and multiplication. In other words, there's no large set of "positive complex numbers" closed under both operations.
This is also the reason why the math in this XKCD strip doesn't actually work.
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