Jiro comments on Lifestyle interventions to increase longevity - Less Wrong
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I think the best we can hope in this context is to have a number of distinct and precise metrics--like nutrients per calorie, nutrients per dollar and nutrients per bulk--, feed these to intuition, and decide accordingly. In other words, when it comes to food, I think we should make decisions according to a "rational" rather than a "quantified" model, given the difficulties of coming up with adequate definitions of a "serving size". Your approach wouldn't work, I believe, because how much people eat of a given food often depends on the presence or absence of other complement and substitute foods.
Googling quickly brings up http://www.cnpp.usda.gov/Publications/NutritionInsights/insight11.pdf
Serving size is defined as follows:
While the amount of food people would eat is not the only factor used, it's a major one.