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ChristianKl comments on Open Thread, January 4-10, 2016 - Less Wrong
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Multiple people such as gwern and Seth Roberts found that the timing makes a difference for them.
That's true.
What I meant is that blood levels of vitamin D are fairly stable and for the purposes of reduction in mortality it shouldn't matter when in the day do you take it. However side-effects, e.g. affecting sleep, are possible and may be a good reason to take it at particular times.
I don't think it's clear at all the the purpose of the reduction of mortality is different than the purpose of sleep quality.
Vitamin D does do different things but I would estimate that a lot of the reduction of mortality is due to having a better immune system. Sleeping badly means a worse immune system.