This came up as a tangent from this question, which is itself a tangent from a discussion on The Hidden Complexity of Wishes.
Suppose we have a perfect cubical box of length 1 meter containing exactly 1 mol of argon gas at room temperature.
- At t=0, the gas is initialized with random positions and velocities drawn from the Maxwell-Boltzmann distribution.
- Right after t=0 we perturb one of the particles by 1 angstrom in a random direction to get the state .
- All collisions are perfectly elastic, so there is no viscosity [edit, this is wrong; even ideal gases have viscosity] and energy is conserved.
- For each possible perturbation, we run physics forward for 20 seconds and measure whether there are more gas molecules in the left side or right side of the box at t=20 seconds (the number on each side will be extremely close to equal, but differ slightly). Do more than 51% of the possible perturbations result in the same answer? That is, if is the predicate "more gas molecules on the left at t=20", is ?
This is equivalent to asking if an omniscient forecaster who knows the position and velocity of all atoms at t=0 except for 1 angstrom of uncertainty in 1 atom can know with >51% confidence which side has more gas molecules at t=20.
I think the answer is no, because multiple billiard balls is a textbook example of a chaotic system that maximizes entropy quickly, and there's no reason information should be preserved for 20 seconds. This is enough time for each atom to collide with others millions of times, and even sound waves will travel thousands of meters and have lots of time to dissipate.
@habryka thinks the answer is yes and the forecaster could get more than 99.999% accuracy, because with such a large number of molecules, there should be some structure that remains predictable.
Who is right?
Standing waves of pressure (a.k.a. sound resonances) are macroscopic patterns with some persistence. Their amplitudes would be really low (≈kT of sound energy per resonance) in a random initial configuration, but if you knew every particle, you would still know the starting amplitude and phase of each standing wave, and could project it out, and one particle won’t appreciably affect the starting amplitude and phase I think.
So, do the standing waves have enough persistence to matter? How much do those standing waves decay after 20 seconds? I dunno. I know how to calculate all the frequencies, but I have no idea how to calculate the Q-factors—at least, not off the top of my head.
I'm also not sure which standing waves (if any?) bear on left-right difference in particle count.
All this is on the edge of my knowledge, so I could well be wrong. Insert "I thinks" and "from what I remembers" as appropriate throughout what follows.
If we start with non-interacting air molecules then the standing waves of pressure are the normal modes of the container. With non-interacting molecules the movement of a single molecule is not necessarily chaotic, whether it is or not depends on the shape of the container.
Assuming no loss (Q factor of infinity) then, knowing that the motion contains some contribution from a particular normal mode allows us... (read more)