I am looking for some understanding into why this claim is made.
As far as I can tell, Löb's Theorem does not directly make such an assertion.
Reading the Cartoon's Guide to Löb's Theorem, it appears that this assertion is made on the basis of the reasoning that Löb's Theorem itself can't prove negations, that is, statements such as "1 + 3 /= 5."
Alas, this means we can't prove PA sound with respect to any important class of statements.
This is a statement that [due to the presence of negations in it] itself can't be proven within PA.
Now it seems that it is being argued that the inability to do this is a bad thing [that is, being able to prove that we can't prove PA sound with respect to any 'important' class of statements].
I think this is actually a very critical question and I have some ideas for what the central crux is here, but I'd be interested in seeing some answers before delving into that.
□(□P→P)→□P→P makes sense to me. Just let P = □P→P.
In other words, P = "If this statement has proof, it is true."
Consider that "If I can write a proof of P, then P has been proven" is simply true.
Therefore, I have written a proof of the statement "If I can write a proof of P, then P has been proven", which means it has been proven. Let that statement = P. So I have that □(□P→P). Since this statement is also true, we have that □P→P.
On the whole of it, we'd certainly want □P to have something to do with P, no? Why wouldn't we expect □P to tell us anything at all about P?