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I of course have an eye on the emotional wellbeing of the children. But I'm not really clear what kind of emotional hurt you mean. Being exposed to e.g. be the loner possibly? I probably wouldn't try it in this relatively direct way if the group weren't that small (4 children) when I can keep the discourse inspirational and playful at all time.
Yes. Getting children to openly state: "We can't be best friend because you are best friends with X" seems to ask for trouble but if you have enough presence in the room to keep the discourse inspirational and playful it might be fine.