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How often do they actually execute those arrested for buying drugs, as opposed to other punishments? Is the chance of "success" even bigger than that of suicide by hanging, for example? Because ending up imprisoned is not necessarily better than ending up mutilated. On the other hand, if someone is going to purchase illegal drugs for an overdose, is there any reason not to do it in a country with capital punishment as opposed to one in which they'd definitely face years in prison? (OK, those aren't the only two options...)
Singapore was used as the specific example because execution is mandatory for certain quantities and they have a track record of staying true to that. The main issue is rather that in countries like Singapore, there is minimal demand for drugs relative to countries with worse law enforcement, lowering the criminal profitability.